In an advance that could push cheap, ubiquitous solar power closer to reality, University of Michigan researchers have found a way to coax electrons to travel much further than was previously thought possible in the materials often used for organic solar cells and other organic semiconductors.
“For years, people had treated the poor conductivity of organics as an unavoidable fact, and this shows that that’s not always the case,” said Stephen Forrest, the Peter A. Franken Distinguished University Professor of Engineering and Paul G. Goebel Professor of Engineering at U-M, who led the research.
Unlike the inorganic solar cells widely used today, organics can be made of inexpensive, flexible carbon-based materials like plastic. Manufacturers could churn out rolls of them in a variety of colors and configurations, to be laminated unobtrusively into almost any surface. Organics’ notoriously poor conductivity, however, has slowed research. Forrest believes this discovery could change the game. The findings are detailed in a paper published online January 17, 2018 in the journal Nature.
The team showed that a thin layer of fullerene molecules—the curious round carbon molecules also called Buckyballs—can enable electrons to travel up to several centimeters from the point where they’re knocked loose by a photon. That’s a dramatic increase; in today’s organic cells, electrons can travel only a few hundred nanometers or less.
Electrons, moving from one atom to another, make up the electric current in a solar cell or electronic component. Materials like silicon, used in today’s inorganic solar cells and other semiconductors, have tightly bound atomic networks that make it easy for electrons to travel through the material. But organic materials have much looser bonds between individual molecules, which can trap electrons. This has long been an Achilles’ heel of organics, but the new discovery shows that it may be possible to tweak their conductive properties for specific applications.
The ability to make electrons move more freely in organic semiconductors could have far-reaching implications. For example, the surface of today’s organic solar cells must be covered with a conductive electrode that collects electrons at the point where they’re initially generated. But freely moving electrons can be collected far away from their point of origination. This could enable manufacturers to shrink the conductive electrode into an invisible grid, paving the way for transparent cells that could be used on windows and other surfaces.
“This discovery essentially gives us a new knob to turn as we design organic solar cells and other organic semiconductor devices,” said Quinn Burlingame, a U-M electrical engineering and computer science graduate researcher and author on the paper. “The possibility of long-range electron transport opens up a lot of new possibilities in device architecture.”
Burlingame says that the initial discovery of the phenomenon came as something of an accident as the team was experimenting with organic solar cell architecture in hopes of boosting efficiency. Using a common technique called vacuum thermal evaporation, they layered in a thin film of C60 fullerenes—each made of 60 carbon atoms—on top of an organic cell’s power-producing layer, where the photons from sunlight knock electrons loose from their associated molecules. On top of the fullerenes, they put another layer to prevent the electrons from escaping.
They discovered something they’d never seen before in an organic—electrons were skittering unfettered through the material, even outside the power-generating area of the cell. Through months of experimentation, they determined that the fullerene layer formed what’s known as an energy well—a low-energy area that prevents the negatively charged electrons from recombining with the positive charges left behind in the power-producing layer.
“You can imagine an energy well as sort of a canyon—electrons fall into it and can’t get back out,” said Caleb Coburn, a graduate researcher in the U-M physics department and an author on the paper. “So they continue to move freely in the fullerene layer instead of recombining in the power-producing layer, as they normally would. It’s like a massive antenna that can collect an electron charge from anywhere in the device.”
Forrest cautions that widespread use of the discovery in applications like solar cells is theoretical at this point. But, he is excited by the discovery’s larger implications for understanding and exploiting the properties of organic semiconductors.
“I believe that ubiquitous solar power is the key to powering our constantly warming and increasingly crowded planet, and that means putting solar cells on everyday objects like building facades and windows,” Forrest said. “Technology like this could help us produce power in a way that’s inexpensive and nearly invisible.”
The paper is titled “Centimeter-Scale Electron Diffusion in Photoactive Organic Heterostructures.” The research was supported by the United States Department of Energy SunShot Program and by the Air Force Office of Scientific Research.